There were six professional wrestling matches on the event's card. Opening the show was a Divas Championship and Women's Championship Unification match between the Divas Champion Beth Phoenix and the Women's Champion Kharma. Following this match was an Elimination Fatal Four Way between Randy Orton, Wade Barrett, Sheamus and Brock Lesnar for the Intercontinental Championship. Third on the card was a Tornado Tag Team TLC match between Dolph Ziggler and Daniel Bryan (Team D-Z) and Justin Gabriel and Tyson Kidd for the WWE Tag Team Championships. Fourth on the card was a 10 minute Championship Scramble between Mason Ryan, Ricky Steamboat, John Cena, Kofi Kingston and Rey Mysterio for the United States Championship. The first main event was a fatal four way TLC match between Edge, Big Show, Alberto Del Rio and The Miz for the World Heavyweight Championship and the second main event was an Armageddon Hell in a Cell match between CM Punk, Stone Cold, Batista, Shawn Michaels, Daniel Bryan and The Rock for the WWE Championship.
In the first match of the night, Beth Phoenix quickly defeated Kharma to unify both the Divas Championship and the Women's Championship. Wade Barrett eliminated all three competitors in the Elimination Fatal Four Way match to win the Intercontinental Championship, and he last eliminated the former champion, Randy Orton.
Team D-Z, which consists of Dolph Ziggler and Daniel Bryan, managed to retain their WWE Tag Team Championships against the newly-formed team of Justin Gabriel and Tyson Kidd in the Tornado Tag Team TLC match. In the fourth match, Mason Ryan had no trouble in retaining his United States Championship against Ricky "The Dragon" Steamboat, John Cena, Kofi Kingston and Rey Mysterio as no successful pinfalls or submissions occurred in that match.
In the World Heavyweight Championship TLC match, Edge took advantage of opportunity and whilst everyone else was down, he climbed up the ladder and retained the World Heavyweight Championship. In the main event, Daniel Bryan surprisingly defeated the former champion CM Punk, Stone Cold, Batista, Shawn Michaels and The Rock in the two out of three falls Armageddon Hell in a Cell match, and won the WWE Championship.
|1||Beth Phoenix (Divas Champion) defeated Kharma (Women's Champion)||Singles match to unify the Women's Championship and the Divas Championship||3:20|
|2||Wade Barrett defeated Randy Orton (c), Sheamus and Brock Lesnar||Elimination Fatal Four Way for the Intercontinental Championship||7:50|
|3||Dolph Ziggler and Daniel Bryan (Team D-Z) (c) defeated Justin Gabriel and Tyson Kidd||Tornado Tag Team TLC match for the WWE Tag Team Championships||4:52|
|4||Mason Ryan (c) defeated Ricky "The Dragon" Steamboat, John Cena, Kofi Kingston and Rey Mysterio||10 minute Championship Scramble for the United States Championship||10:00|
|5||Edge (c) defeated Big Show, Alberto Del Rio and The Miz||Fatal Four Way TLC match for the World Heavyweight Championship||6:30|
|6||Daniel Bryan defeated CM Punk (c), Stone Cold, Batista, Shawn Michaels and The Rock||2 out of 3 falls Armageddon Hell in a Cell match for the WWE Championship||10:42|
Intercontinental Championship Eliminations
|Order of Elimination||Wrestler||Eliminated By||Method of Elimination||Time|
|1||Sheamus||Wade Barrett||Pinned after a kick to the gut and an elbow to the back of the head||4:26|
|2||Brock Lesnar||Wade Barrett||Pinned after a Wasteland||5:31|
|3||Randy Orton||Wade Barrett||Pinned after a chair shot to the head||7:50|
- - There were no pinfalls or submissions in the Championship Scramble.