This was the first "Night of Champions" event to take place in the WTX Universe. The event that came before it was August blockbuster, SummerSlam 2012. It was followed by one of two October PPV events, Hell in a Cell 2012.
There were six professional wrestling matches on the event's card. Opening the card is a singles match between Zack Ryder and Wade Barrett in an Intercontinental Championship rematch from the 100th episode. Following this is a tag team match between Matt Hardy and Jeff Hardy (The Hardy Boyz), and Dolph Ziggler and Daniel Bryan (Team D-Z) for the World Tag Team Championships. Third match on the card is a Elimination Tornado Tag Falls Count Anywhere match between Justin Gabriel & Tyson Kidd, and Curt Hawkins & Tyler Reks for the WWE Tag Team Championships. Following this match is a 20 minute Championship Scramble involving Eddie Guerrero, Samoa Joe, Paul Burchill, Edge and Randy Orton and this is for the World Heavyweight Championship. The fifth match is a pin and submission only 6-man battle royal involving CM Punk, Chris Jericho, Rob Van Dam, Kofi Kingston, Kurt Angle and Austin Aries and this is for the United States Championship. The main event of the pay-per-view is a Last Man Standing match between The Undertaker and Bobby Roode for the WWE Championship.
In the first match, Zack Ryder defeated Wade Barrett after hitting a neckbreaker to win the Intercontinental Championship. Following the first match, Dolph Ziggler and Daniel Bryan (Team D-Z) defeated Matt and Jeff (The Hardy Boyz) via disqualification, thus winning the match, but not the World Tag Team Championships. Third match was Curt Hawkins and Tyler Reks defeating Justin Gabriel and Tyson Kidd after eliminating both Gabriel and Kidd to win the WWE Tag Team Championships.
Following this was the Championship Scramble in which Eddie only just won, by getting a pin in the last 30 seconds of the match, to retain his World Heavyweight Championship. Next was the battle royal where Kurt Angle was the last man standing after all the other competitors had been eliminated, thus winning the United States Championship. In the main event, Bobby Roode surprisingly managed to incapacitate The Undertaker, and Undertaker could not answer the referee's count of ten, thus Bobby Roode won the WWE Championship.
|1||Zack Ryder (c) def. Wade Barrett||Singles match for the Intercontinental Championship||5:39|
|2||"Team D-Z" Dolph Ziggler & Daniel Bryan def. "The Hardy Boyz" Matt Hardy & Jeff Hardy (c) via disqualification||Tag team match for the World Tag Team Championships||6:21|
|3||Curt Hawkins & Tyler Reks def. Justin Gabriel & Tyson Kidd (c)||Elimination Tornado Tag Falls Count Anywhere match for the WWE Tag Team Championships||6:31|
|4||Eddie Guerrero (c) def. Samoa Joe, Paul Burchill, Edge and Randy Orton||20-minute Championship Scramble for the World Heavyweight Championship||20:00|
|5||Kurt Angle def. CM Punk (c), Chris Jericho, Rob Van Dam, Austin Aries and Kofi Kingston||6-man pinfall and submission only battle royal for the United States Championship||9:34|
|6||Bobby Roode def. The Undertaker (c)||Last Man Standing match for the WWE Championship||8:20|
|Elimination Number||Wrestler||Team||Eliminated By||Method of Elimination||Time|
|1||Justin Gabriel||Gabriel & Kidd||Tyler Reks||Submitted after a Camel Clutch||4:04|
|2||Tyson Kidd||Gabriel & Kidd||Curt Hawkins||Pinned after a back superplex off the top rope||6:31|
Championship Scramble Pinfalls and Submissions
|1||Samoa Joe||2||Paul Burchill||Submitted after a Coquina Clutch||4:47|
|2||Edge||3||Paul Burchill||Pinned after a spinning heel kick||8:41|
|3||Samoa Joe||2||Paul Burchill||Submitted after a Coquina Clutch||9:22|
|4||Randy Orton||4||Samoa Joe||Pinned after a knee to the back||10:34|
|5||Samoa Joe||2||Edge||Submitted after a Coquina Clutch||18:03|
|Winner||Eddie Guerrero||6||Samoa Joe||Pinned after a Brainbuster||19:36|
Battle Royal Eliminations
|Order of Elimination||Wrestler||Eliminated By||Method of Elimination||Time|
|1||Austin Aries||CM Punk||Pinned after a Swinging Neckbreaker||7:00|
|2||Kofi Kingston||Rob Van Dam||Pinned after executing a bridging pin||7:13|
|3||CM Punk||Kurt Angle||Pinned after an Angle Slam||8:08|
|4||Chris Jericho||Rob Van Dam||Pinned after a Standing Moonsault||9:12|
|5||Rob Van Dam||Kurt Angle||Pinned after an elbow to the back of the head||9:34|